• 文献标题:   Reduction of graphene oxide at the interface between a Ni layer and a SiO2 substrate
  • 文献类型:   Article
  • 作  者:   TANAKA H, OBATA S, SAIKI K
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Univ Tokyo
  • 被引频次:   18
  • DOI:   10.1016/j.carbon.2013.03.041
  • 出版年:   2013

▎ 摘  要

Reduction of graphene oxide (GO) was carried out on SiO2 using a thin Ni overlayer as a catalyst. A Ni/GO/SiO2 structure was heated at 800 degrees C in high vacuum for 6 min. After removing the Ni overlayer, formation of graphene was confirmed by Raman spectroscopy. For the Ni overlayer thinner than 40 nm, GO was reduced to graphene on-site. For the thicker Ni overlayer, however, GO was completely decomposed and graphene was formed in a segregation and/or precipitation process. The use of GO with a thin Ni overlayer enabled on-site and transfer-free fabrication of graphene without use of such flammable gases as methane and hydrogen. (C) 2013 Elsevier Ltd. All rights reserved.