• 文献标题:   Carbon-coated MoO2 dispersed in three-dimensional graphene aerogel for lithium-ion battery
  • 文献类型:   Article
  • 作  者:   ZHOU Y, LIU Q, LIU DB, XIE H, WU GX, HUANG WF, TIAN YF, HE Q, KHALIL A, HALEEM YA, XIANG T, CHU WS, ZOU CW, SONG L
  • 作者关键词:   moo2 nanoparticle, carboncoated, threedimensional graphene aerogel, lithiumion battery
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Univ Sci Technol China
  • 被引频次:   37
  • DOI:   10.1016/j.electacta.2015.05.153
  • 出版年:   2015

▎ 摘  要

Three-dimensional (3D) nanoarchitectures can improve the performance of electrical energy storage systems. In this paper, combining an improved solvothermal method with calcination treatment, thin layer carbon-coated MoO2 nanoparticles with the size of 20-50 nm were uniformly dispersed in 3D graphene aerogel (abbreviated as MoO2@C-Gas). The hybrid materials were subsequently used as a new-structured anode for lithium-ion batteries (LIBs), yielding high reversible capacity with excellent stable cyclability. We found that the battery with MoO2@C-Gas electrode could deliver a discharge capacity of 1515 mAhg(-1) at a current density of 80 mAg(-1) in the first cycle, and remain at 1113 mAhg-1 over 60 cycles. Furthermore, with the increase of current density, it also exhibited a high rate of capability and good cycling performance. The outstanding performance of the hybrid electrode were attributed to the unique 3D aerogel morphology and the close combination between C@MoO2 and graphene layers, which could significantly improve the anode's electronic conductivity. (C) 2015 Elsevier Ltd. All rights reserved.