• 文献标题:   Construction of Zeolite/Fe2ZnTiO6/graphene oxide multifunctional nanocomposite with high efficiency for photocatalytic removal of inorganic pollutants under visible irradiation
  • 文献类型:   Article
  • 作  者:   ALIZADEH T, KADKHODAYAN H
  • 作者关键词:   toxic heavy metal, zeolite, graphene oxide, double perovskite, photocatalysi
  • 出版物名称:   JOURNAL OF PHYSICS CHEMISTRY OF SOLIDS
  • ISSN:   0022-3697 EI 1879-2553
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.jpcs.2022.110997 EA SEP 2022
  • 出版年:   2022

▎ 摘  要

Nowadays, pollutants of toxic heavy metals (THMs), nitrate (NO3- ), and carbon dioxide (CO2) are three types of important environmental pollutants that have become a global concern. In recent years, perovskite photocatalysts have created great development prospects in pollutants treatment of aqueous solutions, industrial wastewaters, and air. Herein, Zeolite/Fe2ZnTiO6 (FZTO) double perovskite/graphene oxide (GO) nanocomposite (NC) was prepared as a highly efficient multifunctional perovskite photocatalyst by the sol-gel method. The crystal structure, morphology, and composition of the synthesized nanocomposite were characterized by XRD, SEM, and EDX-Map analysis. Also, photocatalytic mechanisms of the Zeolite/Fe2ZnTiO6/graphene oxide nanocomposite were evaluated by PL, DRS, and UV-visible analysis. Photocatalytic activity of Zeolite/Fe2ZnTiO6/ graphene oxide nanocomposite was evaluated for the removal of toxic heavy metals, nitrate, and carbon dioxide pollutants in experiment conditions including pH (1-9), the temperature (25-65 degrees C), stirring speed (100-500 rpm), retention time (1-6 h), photocatalyst dosage (0.25-1.5 g/l), pollutants concentration (5-120 mg L-1) and distance between the visible source and solution surface (5-20 cm). The UV-visible spectrums were shown the removal efficiency of 90% for toxic heavy metals in optimal conditions of pH;7, temperature; 25 degrees C, stirring speed; 200 rpm, retention time; 5h, photocatalyst dosage; 1 g/l, THMs concentration; 10 mg L-1, and distance between the light source and solution surface; 10 cm under visible light irradiation. Also, the highest degradation efficiency of NO3- pollutant from aqueous solution was determined at about 85% in optimized conditions of pH; 3, temperature; 25 degrees C, agitation rate; 200 rpm, reaction time; 5h, photocatalyst dosage; 1 g/l, NO3- concentration; 100 mg L-1, and distance between the surface of the solution and light source; 10 cm under visible light irradiation. Finally, conversion maximum of CO2 pollutant was obtained at about 80% in optimum conditions of pH; 3, temperature; 25 degrees C, mixing rate; 200 rpm, retention time; 5h, photocatalyst dosage; 1 g/l, CO2 concentration; 100 mg L-1, and distance between the solution surface and light source; 10 cm under visible light irradiation.