• 文献标题:   Surface functionalization of graphene oxide by sulfonation method to catalyze the synthesis of furfural from sugarcane bagasse
  • 文献类型:   Article, Early Access
  • 作  者:   HUONG LM, TRUNG TQ, TUAN TT, VIET NQ, DAT NM, NGHIEM DG, THINH DB, TINH NT, OANH DTY, PHUONG NT, NAM HM, PHONG MT, HIEU NH
  • 作者关键词:   graphenebased material, sulfonated graphene oxide, furfural, sugarcane bagasse
  • 出版物名称:   BIOMASS CONVERSION BIOREFINERY
  • ISSN:   2190-6815 EI 2190-6823
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1007/s13399-021-02272-5 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

Recently, graphene-based material as a catalyst has crucially shown a novel strategy in furfural synthesis from biomass resources. In this study, sulfonated graphene oxide (SGO) was studied within five different graphene oxide to sulfanilic acid mass ratios of 1:1.5, 1:2.0, 1:2.5, 1:3.0, and 1:3.5 for facile synthesis of furfural from sugarcane bagasse. The structural investigation of those samples was proceeded through Fourier transform infrared spectroscopy, Raman spectroscopy, and energy-dispersive X-ray spectroscopy. The appropriate sample with the sulfur mass percentage of 3.51 %, corresponding to the ratio of 1:3.5, gives out the highest furfural yield was then, conducted with X-ray diffraction, Scanning electron microscopy, Transmission electron microscopy, and Brunauer-Emmett-Teller for further morphological analysis. The influence of catalyst dose, reaction temperature, and time on the yield of furfural using this catalyst revealed that under reaction conditions of 190 degrees C for 90 min, reaction in a low dose of 5 wt% of SGO solution gave out the highest conversion of furfural (20.6 %). According to the results, SGO showed high application potential for the synthesis of furfural from sugarcane bagasse.