• 文献标题:   Graphene quantum dots prepared from glucose as optical sensor for glucose
  • 文献类型:   Article
  • 作  者:   SHEHAB M, EBRAHIM S, SOLIMAN M
  • 作者关键词:   graphene, graphene quantum dot, optical sensor, photoluminance, glucose sensor
  • 出版物名称:   JOURNAL OF LUMINESCENCE
  • ISSN:   0022-2313 EI 1872-7883
  • 通讯作者地址:   Univ Alexandria
  • 被引频次:   43
  • DOI:   10.1016/j.jlumin.2016.12.006
  • 出版年:   2017

▎ 摘  要

Quantum Dots (QDs) show promise materials for many technological applications. In this work we utilized a simple route to prepare graphene quantum dots (GQDs) using glucose carbonization. GQDs functionalized with phenylboronic add receptors were employed as a sensing material for a nonenzymatic glucose sensor. Photoluminance spectra of GQDs were used as a property of optical sensor for glucose. GQDs considered as a good sensing probe because of its low toxicity, high photoluminance, water solubility and excelent photochemical properties. The prepared GQDs were characterized using UV-visible, Raman and photoluminance spectroscopies, X-ray diffraction and high resolution transmission electron microscopy (HRTEM). HRTEM micrographs confirmed the preparation of 7-10 nm GQDs and the emission peak of the GQDs appeared at 450 nm. The developed sensor has linear response to glucose over a concentration range of 4-40 mM with a correlation coefficient of 0.97 and a low detection limit of approximately 3.0 mM. (C) 2016 Elsevier B.V. All rights reserved.