• 文献标题:   Wrapping mesoporous Fe2O3 nanoparticles by reduced graphene oxide: Enhancement of cycling stability and capacity of lithium ion batteries by mesoscopic engineering
  • 文献类型:   Article
  • 作  者:   YANG ZW, HUANG Y, YAO FL, LUO HL, WAN YZ
  • 作者关键词:   mesopore, metal oxide, reduced graphene oxide, nanocomposite, lithium ion battery
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   East China Jiaotong Univ
  • 被引频次:   6
  • DOI:   10.1016/j.ceramint.2018.08.058
  • 出版年:   2018

▎ 摘  要

The fast capacity fading at high current density turns out to be one of the key challenges limiting the broad applications of transition metal oxide-based electrodes. Herein, Fe2O3 nanoparticles with well-defined mesopores wrapped by reduced graphene oxide (RGO) have been synthesized via a facile hydrothermal strategy. The as-prepared nanocomposites were systematically characterized. XPS and Raman analyses confirm the co-existence of Fe2O3 and RGO in the nanocomposite system. SEM and TEM reveal that the mesoporous Fe2O3 nanoparticles have a size of 20-60 nm and are uniformly dispersed and tightly wrapped by RGO. When used as the anode in lithium ion batteries, the mesoporous-Fe2O3/RGO electrode exhibits excellent cycling stability (1098 mA h g(-1) after 500 cycles at 1 A g(-1)) and superior rate capability (574 mA h g(-1) at 5 A g(-1)). The excellent electrochemical performance can be mainly ascribed to the unique mesoscopic architecture that serves as a cushion to alleviate volume change of Fe2O3 during discharge/charge cycles, provides a sustainably large contact area with the electrolyte, and improves electrical conductivity. This unique nanocomposite electrode holds great potential as an anode material for advanced lithium ion batteries.