• 文献标题:   Remarkable reusability of magnetic Fe3O4-graphene oxide composite: a highly effective adsorbent for Cr(VI) ions
  • 文献类型:   Article, Early Access
  • 作  者:   MAHVI AH, BALARAK D, BAZRAFSHAN E
  • 作者关键词:   cr vi, fe3o4go, regeneration, thermodynamic
  • 出版物名称:   INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY
  • ISSN:   0306-7319 EI 1029-0397
  • 通讯作者地址:  
  • 被引频次:   18
  • DOI:   10.1080/03067319.2021.1910250 EA APR 2021
  • 出版年:   2021

▎ 摘  要

The removal of Hexavalent Chromium (Cr (VI)) is a challenging task due to its acute toxicity even at low concentration. In the present study, graphene oxide-Fe3O4 composite (Fe3O4-GO) was prepared and utilised for the removal of Cr(VI) from aqueous solution. Batch experiments were conducted to investigate the influence of operating variables. Transmission electron microscopy (TEM), Brunauer-Emmett-Teller (BET), X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), vibrating sample magnetometer (VSM), and point zero charge (pH(pzc)) were used to characterise the Fe3O4-GO. BET surface area of GO was 254.2 m(2)/g, but for Fe3O4-GO, it was decreased to 194.6 m(2)/g. From the experimentation, it was found that the best conditions were presented at 45 degrees C, 0.6 g/L, Fe3O4-GO mass, PH = 2, concentration 10 mg/L, and contact time = 60 min with removal efficiencies above 99%. Analyses of Cr(VI) adsorption kinetics exhibited relatively rapid adsorption behaviour and obedience of the data from pseudo-second-order kinetics. The Langmuir model resulted in best fits to the adsorption isotherms for both linear and nonlinear models with maximum adsorption of 140.8 mg/g. The adsorption of Cr(VI) was an endothermic and spontaneous process. The removal efficiencies exhibited a moderate reduction in the maximum values (less than 6%) after six regeneration cycles. The Fe3O4-GO composite could be a promising material for the removal of Cr(VI) from wastewater.