• 文献标题:   Reduced porous carbon/N-doped graphene nanocomposites for accelerated conversion and effective immobilization of lithium polysulfides in lithium-sulfur batteries
  • 文献类型:   Article
  • 作  者:   ZHANG MJ, ZHANG ZS, LI F, MAO HS, LIU WJ, RUAN DS, JIA XY, YANG Y, YU XY
  • 作者关键词:   porous material, ndoped graphene, nanocomposite, lithium sulfur batterie
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   6
  • DOI:   10.1016/j.electacta.2021.139268 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

Lithium sulfur (Li-S) batteries have been foreseen as the next generation energy storage device because of their high theoretical energy density. However, a low-cost, efficient and replicable way for mass producing suitable host materials that enable high-performance Li-S batteries is still a huge challenge. To tackle this issue, a rPC-NG composite was fabricated by mixing reduced porous carbon material (rPC) prepared from PAN fiber and N-doped graphene (NG) through a simple and scalable ball milling process. Herein, the rPC and NG immobilize sulfur via strong physical and chemical adsorption and inhibit the shuttle effect of lithium polysulfides (LiPSs) successfully. Importantly, such composite possesses a layered porous structure which can contribute to a high loading of sulfur, leading to the excellent conductivity, outstanding utilization rate and stability of adsorbed sulfur. The resultant rPC-NG/S cathode exhibits a stable cycling performance (503 mAh g(-1) at 0.5 C after 500 cycles and 770 mAh g(-1) at 0.2 C after 200 cycles) and high rate performance (540 mAh g(-1) at 2 C). (C) 2021 Elsevier Ltd. All rights reserved.