• 文献标题:   NHC-Pd complex heterogenized on graphene oxide for cross-coupling reactions and supercapacitor applications
  • 文献类型:   Article
  • 作  者:   KANDATHIL V, SIDDIQA A, PATRA A, KULKARNI B, KEMPASIDDAIAH M, SASIDHAR BS, PATIL SA, ROUT CS, PATIL SA
  • 作者关键词:   graphene oxide, hiyama crosscoupling, nheterocyclic carbenepalladium ii, supercapacitor, suzukimiyaura crosscoupling
  • 出版物名称:   APPLIED ORGANOMETALLIC CHEMISTRY
  • ISSN:   0268-2605 EI 1099-0739
  • 通讯作者地址:   Jain Univ
  • 被引频次:   0
  • DOI:   10.1002/aoc.5924 EA JUL 2020
  • 出版年:   2020

▎ 摘  要

N-heterocyclic carbene (NHC)-palladium(II) complex (GO@NHC-Pd) was synthesized on graphene oxide (GO) support via a simple and cost-effective multistep approach. The spectroscopic, microscopic, thermal, and surface analyses of GO@NHC-Pd confirmed the successful formation of the catalyst. The investigation of catalytic activity showed that GO@NHC-Pd was very effective in Suzuki-Miyaura as well as Hiyama cross-coupling. Being heterogeneous in nature, GO@NHC-Pd was recovered after each reaction cycle easily and reused for up to nine and six cycles in Suzuki-Miyaura and Hiyama cross-coupling, respectively, without significant loss of activity. Further exploration of the supercapacitor performance of GO@NHC-Pd catalyst assembled in a two-electrode cell configuration shown a maximum attained capacitance of 105.26 F/g at a current density of 0.1 A/g with good cycling stability of 96.89% over 2,500 cycles.