• 文献标题:   Palladium Nanoparticles-Decorated beta-Cyclodextrin-Cyanoguanidine Modified Graphene Oxide: A Heterogeneous Nanocatalyst for Suzuki-Miyaura Coupling and Reduction of 4-Nitrophenol Reactions in Aqueous Media
  • 文献类型:   Article
  • 作  者:   DANESHAFRUZ H, BARANI H, SHEIBANI H
  • 作者关键词:   graphene oxide, palladium nanoparticle, betacyclodextrin, suzukimiyaura, 4nitrophenol
  • 出版物名称:   JOURNAL OF INORGANIC ORGANOMETALLIC POLYMERS MATERIALS
  • ISSN:   1574-1443 EI 1574-1451
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1007/s10904-021-02218-4 EA JAN 2022
  • 出版年:   2022

▎ 摘  要

In this study, graphene oxide used as a stable support to adsorb and stabilize palladium nanoparticles for preparing a heterogeneous nanocatalyst. In order to increase the palladium adsorption, the surface of graphene oxide was functionalized with beta-Cyclodextrin and cyanoguanidine compounds. The prepared nanocatalyst was defined by various characterization techniques such as FT-IR, XRD, TEM, SEM-EDX, ICP and UV-Vis. The catalytic efficiency of the synthesized organic-inorganic nanocomposite investigated by focusing on the Suzuki-Miyaura binding reaction and reduction of 4-nitrophenol to 4-aminophenol, which the nanocatalyst work is easy, affordable, and environmentally safe. The performed reaction showed high yields of biphenyl compounds through the Suzuki-Miyaura reaction and confirms very good conversion of 4-nitrophenol to its reduced form. Also, the proposed nanocatalyst presented significant catalytic efficiency (yield: 98% to 91%) after using five times. [GRAPHICS]