• 文献标题:   Flame synthesis of carbon nanotubes and few-layer graphene on metal-oxide spinel powders
  • 文献类型:   Article
  • 作  者:   MEMON NK, XU FS, SUN GL, DUNHAM SJB, KEAR BH, TSE SD
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Rutgers State Univ
  • 被引频次:   20
  • DOI:   10.1016/j.carbon.2013.07.023
  • 出版年:   2013

▎ 摘  要

Multi-walled and single-walled carbon nanotubes (CNTs) and few-layer graphene (FLG) are grown directly on spinel powders using flame synthesis. CNT and FLG growth occurs via the decomposition of flame-generated carbon precursors (e.g., CO, C2H2, and CH4) over nanoparticles (i.e., Ni, Co, Fe, and Cu) reduced from the solid oxide. The growth of CNTs is investigated on NiAl2O4, CoAl2O4, and ZnFe2O4, using counterflow diffusion flame and multiple inverse-diffusion flames (m-IDFs), while the growth of FLG is investigated on CuFe2O4 using m-IDFs. As shown by analytical electron microscopy techniques, Raman spectroscopy, and X-ray diffraction, substrate temperature and spinel composition play critical roles in the growth of both CNTs and FLG. (C) 2013 Elsevier Ltd. All rights reserved.