• 文献标题:   Preparation of polyimide/amino-modified reduced graphene oxide composite matrix and its application in UV-cured functionalized films
  • 文献类型:   Article
  • 作  者:   ZHENG XF, LIU JC, WANG K, LIU R, YUAN Y, LIU XY
  • 作者关键词:   polyimide, amg, composite matrix, uvcured, functionalized film
  • 出版物名称:   PROGRESS IN ORGANIC COATINGS
  • ISSN:   0300-9440
  • 通讯作者地址:   Jiangnan Univ
  • 被引频次:   5
  • DOI:   10.1016/j.porgcoat.2018.08.002
  • 出版年:   2018

▎ 摘  要

Polyimide/amino-modified reduced graphene oxide (PI/AMG) composite matrix were synthesized through the condensation reaction of 4,4'-diaminodiphenyl ether, 3,5-diaminobenzoic acid, diphthalic anhydride, and AMG. Subsequently, the double bonds were incorporated into the matrix through the reaction of glycidyl methacrylate (epoxide group) and the carboxyl group on PI/AMG. UV-cured composite films were then prepared and performance was evaluated. The results revealed that the tensile strength and elongation at break could reach a maximum of 108.7 MPa and 46.4%, which represented increases of 102.8% and 354.9%, respectively, compared with the GPI/AMG(0%) film. The water absorption decreased from 0.64% to 0.27%. And their surface resistivity reached 10(6)-10(9) Omega, an increase of approximately eight orders of magnitude.