• 文献标题:   Plasma-induced grafting of polyacrylamide on graphene oxide nanosheets for simultaneous removal of radionuclides
  • 文献类型:   Article
  • 作  者:   SONG WC, WANG XX, WANG Q, SHAO DD, WANG XK
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   North China Elect Power Univ
  • 被引频次:   91
  • DOI:   10.1039/c4cp04289a
  • 出版年:   2015

▎ 摘  要

Polyacrylamide (PAM) grafted graphene oxide (denoted as PAM/GO) was synthesized by the plasma-induced polymerization technique and applied as an adsorbent for the simultaneous removal of radionuclides from radioactive wastewater. The interactions of PAM/GO with the radionuclides U(VI), Eu(III) and Co(II) were studied, along with their sorption kinetics. The results indicated that radionuclide sorption on PAM/GO was affected by the solution pH and ionic strength. The maximum sorption capacities of U(VI), Eu(III) and Co(II) on PAM/GO (0.698, 1.245 and 1.621 mmol g(-1), respectively) at pH = 5.0 +/- 0.1 and T = 295 K were much higher than those of radionuclides on GO and other adsorbents. The thermodynamic data (Delta H-0, Delta S-0 and Delta G(0)) calculated from the temperature-dependent sorption isotherms suggested that the sorption of radionuclides on PAM/GO was a spontaneous and endothermic process. These results indicate that PAM/GO is a promising material for the control of radionuclide pollution.