• 文献标题:   Highly Conductive Freestanding Graphene Films as Anode Current Collectors for Flexible Lithium-Ion Batteries
  • 文献类型:   Article
  • 作  者:   RANA K, SINGH J, LEE JT, PARK JH, AHN JH
  • 作者关键词:   flexible current collector, cvd, binderfree electrode, graphene, mos2, liion battery
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   33
  • DOI:   10.1021/am500996c
  • 出版年:   2014

▎ 摘  要

The electrodes in lithium-ion batteries (LIBs) are typically films that are arranged on metal foil current collectors with a thickness of several tens of pm. Here, we report on the preparation of a thick free-standing graphene film synthesized by CVD as an alternative to Cu foil as an anode current collector. As a model system, MoS2 anodes with a flower-like morphology were anchored onto the surface of the thick graphene film. A hybrid and binder free anode without a conventional metal current collector exhibited an excellent capacity value of around 580 rnAh/g (@50 mA/g) and reasonable charge/discharge cyclability. The work presented here may stimulate the use of graphene films as replacements for conventional current collectors and additive free electrode in LIBs.