• 文献标题:   Sulfonated reduced graphene oxide as a highly efficient catalyst for direct amidation of carboxylic acids with amines using ultrasonic irradiation
  • 文献类型:   Article
  • 作  者:   MIRZAAGHAYAN M, TAVANA MM, BOUKHERROUB R
  • 作者关键词:   sulfonated reduced graphene oxide, carboxylic acid, amine, direct amidation, solid acid catalyst, sonochemical reaction
  • 出版物名称:   ULTRASONICS SONOCHEMISTRY
  • ISSN:   1350-4177 EI 1873-2828
  • 通讯作者地址:   CCERCI
  • 被引频次:   23
  • DOI:   10.1016/j.ultsonch.2015.10.009
  • 出版年:   2016

▎ 摘  要

Sulfonated reduced graphene oxide nanosheets (rGO-SO3H) were prepared by grafting sulfonic acid-containing aryl radicals onto chemically reduced graphene oxide (rGO) under sonochemical conditions. rGO-SO3H catalyst was characterized by Fourier-transform infrared (FT-IR) spectroscopy, Raman spectroscopy, scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and X-ray photoelectron spectroscopy (XPS). rGO-SO3H catalyst was successfully applied as a reusable solid acid catalyst for the direct amidation of carboxylic acids with amines into the corresponding amides under ultrasonic irradiation. The direct sonochemical amidation of carboxylic acid takes place under mild conditions affording in good to high yields (56-95%) the corresponding amides in short reaction times. (C) 2015 Elsevier B.V. All rights reserved.