• 文献标题:   Material- and process-effects on homogeneity and electric properties of transparent conducting films composed of hydrazine-reduced graphene oxide and/or silver nanowire
  • 文献类型:   Article
  • 作  者:   NAITO K, YOSHINAGA N, AKASAKA Y
  • 作者关键词:   transparent conducting film, graphene, silver nanowire, graphene oxide, work function
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Toshiba Co Ltd
  • 被引频次:   2
  • DOI:   10.1016/j.synthmet.2016.03.004
  • 出版年:   2016

▎ 摘  要

Photomicroscope observation of hydrazine-reduced graphene oxide (h-rGO) films indicates that the films prepared by spin-coating are more homogeneous than those prepared by dip-coating. Graphene oxide (GO) is apt to aggregate during the dipping process. Increasing rotation speed of the spin-coating decreased film thickness and increased surface resistant (Rs). Rs of small-sized h-rGO(BF1A) was smaller than that of large-sized h-rGO(NiSiNa). The h-rGO(NiSiNa) films prepared with a rotation number smaller than 2000 rpm had wrinkles about 5 nm in height and particles with about 15 nm height. The rotation number of 3000 rpm decreased the wrinkles and particles resulting in smaller Rs. Increasing the hydrazine-treatment temperature from 90 to 140 degrees C caused the Rs values to decrease. Work-function values of h-rGO(NiSiNa) were 3.6-3.8 eV; smaller than those of other h-rGOs. Larger ratio of pyrrolic nitrogen to oxygen-bound nitrogen gave smaller WF values. Silver nanowire (AgNW) films prepared by multiple spin-coating processes showed small Rs vales and small Rs deviations. Mechanical pressing at 100 degrees C made the thickness of AgNW films equal to the AgNW diameter and decreased the Rs values. Polymer (Cytop) was coated on the AgNW films and the h-rGO/AgNW/Cytop transparent conducting film was peeled off. The arithmetic average roughness of the h-rGO surface was 1.2 nm. (C) 2016 Elsevier B.V. All rights reserved.