• 文献标题:   Cellulose nanofibrils-reduced graphene oxide xerogels and cryogels for dielectric and electrochemical storage applications
  • 文献类型:   Article
  • 作  者:   POTTATHARA YB, BOBNAR V, FINSGAR M, GROHENS Y, THOMAS S, KOKOL V
  • 作者关键词:   cellulose nanofibril, graphene, dielectric paper
  • 出版物名称:   POLYMER
  • ISSN:   0032-3861 EI 1873-2291
  • 通讯作者地址:   Univ Bretagne Sud
  • 被引频次:   6
  • DOI:   10.1016/j.polymer.2018.06.005
  • 出版年:   2018

▎ 摘  要

The effect of structure (density and porosity) and composition (ratio) of composites prepared from cellulose nanofibrils (CNF) and reduced graphene oxide (RGO) as film-like xerogels and porous cryogels, respectively, were investigated related to their dielectric performance and electrochemical storage abilities. A very small content (5 wt%) of RGO incorporated xerogelic film of a denser and layered structure shows relatively high dielectric constant of similar to 85 and similar to 164 and an ac electrical conductivity of 0.0028 S/m(2) and 0.0072 S/m(2) at 270 K and 370 K, respectively, at a high frequency of 1 MHz showing their suitability for high temperature dielectric storage applications. On the other hand, a high specific capacitance of similar to 460 F/g and electrochemical resistance of 12-15 Omega cm(2) was observed for well-aligned and longitudinal-oriented micro-porous cryogel, indicate on its suitability as electrodes for electrochemical storage devices. (C) 2018 Elsevier Ltd. All rights reserved.