• 文献标题:   Degradation of Methylene Blue Dye and Bisphenol-A Using Expanded Graphene-Polypyrrole-Magnetite Nanocomposite
  • 文献类型:   Article
  • 作  者:   AMA OM, AIGBE UO, ANKU WW, OSIBOTE OA, PAL K
  • 作者关键词:   photoelectrochemical degradation, photoanode, contaminant, energy bandgap, nanocomposite
  • 出版物名称:   TOPICS IN CATALYSIS
  • ISSN:   1022-5528 EI 1572-9028
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1007/s11244-022-01626-1 EA MAY 2022
  • 出版年:   2022

▎ 摘  要

This work is focused on the synthesis of expanded graphene (EG), polypyrrole-magnetite (PPy/Fe3O4) and expanded graphene-polypyrrole-magnetite nanocomposite (EG-PPy/Fe3O4) electrodes and their application in the degradation of organic pollutants in water. The nanocomposites were synthesized through the co-precipitation method and characterized using ultraviolet-visible spectroscopy, Brunauer-Emmett-Teller surface area analyser, scanning electron microscope, energy dispersive X-ray, X-ray diffractometer and X-ray photoelectron spectroscope. The EG, PPy/Fe3O4 and EG-PPy/Fe3O4 electrodes were applied in a comparative photoelectrochemical degradation of 0.1 x 10(-4) M methylene blue (MB) dye and bisphenol A (BPA) in 0.1 M Na2SO4 under visible light irradiation. The degradation was also performed through photolysis, electrochemical and photoelectrochemical processes. The results showed that the pure PPy and EG-PPy/Fe3O4 were present in the Anatase phase of PPy. The EG-PPy/Fe3O4 composite absorbed a noticeable amount of light in the entire visible light region compared to pure PPy and PPy/Fe3O4. The surface area and pore volume of pure PPy was observed to decrease after modification with the EG as a result of the interpenetration of the porous matrix of EG by the PPy nanoparticles. The EG-PPy/Fe3O4 electrode was the most effective in the degradation of both dyes. The order of efficiency was EG < PPy/Fe3O4 < EG-PPy/Fe3O4. The photoelectrochemical degradation process resulted in improved degradation efficiency of 92% (MB) and 88% (BPA) within 240 min and was observed to be greater than that of photolysis and electrochemical oxidation methods. The EG-PPy/Fe3O4 photoanode is regarded as an effective material for the degradation of MB and BPA in wastewater. [GRAPHICS]