• 文献标题:   Activation of radical addition to graphene by chemical hydrogenation
  • 文献类型:   Article
  • 作  者:   WHITENER KE, LEE WK, STINE R, TAMANAHA CR, KIDWELL DA, ROBINSON JT, SHEEHAN PE
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   US Naval Res Lab
  • 被引频次:   3
  • DOI:   10.1039/c6ra21113e
  • 出版年:   2016

▎ 摘  要

We report several methods of chemical dehydrogenation of hydrogenated graphene (HG), characterizing the results using Raman, X-ray photoelectron spectroscopy, and electrical conductivity measurements. Notably, the hydrogen-graphene bonds appear to activate the graphene toward subsequent reaction such that, in several cases, the addition of the dehydrogenating agent to the graphene accompanies the removal of hydrogen. We compare the uptake of chemical groups on HG to those on pristine graphene and find that HG reacts more readily than pristine graphene with radical generators such as chlorine and AIBN.