• 文献标题:   Salting Up of Chemically Modified Graphene to Assemble Large-Scale Transparent Conductive Films
  • 文献类型:   Article
  • 作  者:   LEE K, LEE H, RYU S
  • 作者关键词:   graphene, saltingout, transparent conductive film, selfassembly
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   Univ Suwon
  • 被引频次:   0
  • DOI:   10.1166/jnn.2017.15063
  • 出版年:   2017

▎ 摘  要

I report a method for assembling large-scale transparent conductive films (TCFs) through the phenomenon of "salting up" of chemically modified graphene (CMG) in the presence of metallic salts. The method described herein was inspired by the well-known protein purification process, 'salting-out.' In contrast, addition of hydrophobic CMGs to the solution of a salt results in 'salting-up' of CMGs. Owing to the presence of the salt, dehydrated CMG flakes spontaneously form an extremely thin layer at the air-water interface. The salted-up CMGs spontaneously form an extremely thin layer of CMGs at air-water interface, which is a useful method to prepare a conducting film with an extremely largearea. This CMG film can be transferred to any other flexible substrate as a TCF film and be enlarged to a greater scale depending on size of air-water interface. I demonstrate a new way to fabricate TCF film that can be applied in the fabrication of large scale graphene-based electronic devices.