• 文献标题:   Development of graphene oxide-based membrane as a pretreatment for thermal seawater desalination
  • 文献类型:   Article
  • 作  者:   ABDELKADER BA, ANTAR MA, LAOUI T, KHAN Z
  • 作者关键词:   desalination, pretreatment, graphene oxide, polyethersulfone, nanofiltration, top brine temperature
  • 出版物名称:   DESALINATION
  • ISSN:   0011-9164 EI 1873-4464
  • 通讯作者地址:   King Fahd Univ Petr Minerals
  • 被引频次:   3
  • DOI:   10.1016/j.desal.2019.04.028
  • 出版年:   2019

▎ 摘  要

Scaling constitutes a major concern in seawater desalination. In thermal desalination, scaling is limiting the top brine temperature (TBT). Brine temperature limitation depends on the concentration of divalent ions. This paper reports the synthesis of graphene oxide (GO)/polyacrylamide (PAM)/polyethersulfone (PES) membrane, in which GO layer is deposited on the surface of PES substrate using PAM as an adhesive layer, to be used as a pretreatment step to filter the divalent ions in thermal seawater desalination application. GO/PAM-PES membrane is prepared via spin coating technique, then reduced to rGO/PAM-PES by subjecting the membrane to hydrogen iodide (HI). PAM is used as an adhesive layer onto PES membrane (an ultrafiltration membrane) to improve rGO layer attachment onto its surface. The results indicate that increasing pressure increases both the rejection and the permeate flux. Using seawater, rGO/PAM-PES yields a higher rejection for Mg2+ and Ca2+ ions compared with commercial nanofiltration membrane (NF270). The pretreatment step allows the increase in TBT to 148 degrees C using NF, 160 degrees C using NF-GO and 166 degrees C using rGO membranes.