• 文献标题:   Polymer-graphene hybride decorated Pt nanoparticles as highly efficient and reusable catalyst for the dehydrogenation of dimethylamine-borane at room temperature
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   SEN B, KUZU S, DEMIR E, AKOCAK S, SEN F
  • 作者关键词:   dehydrocoupling, onestep chemical assembly, strategy, monodispersity, panicoupled rgo
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Dumlupinar Univ
  • 被引频次:   42
  • DOI:   10.1016/j.ijhydene.2017.05.112
  • 出版年:   2017

▎ 摘  要

Addressed herein, we report a reduced graphene oxide (rGO) nanosheet coupled with polyaniline (PANI) for platinum (Pt) nanoparticles as supporting materials. The PANI-coupled rGO (PANI@rGO) nanosheet is prepared by a simple one-step chemical assembly strategy, and Pt nanoparticles are anchored on the support of PANI@rGO through the reaction of PANI with a platinum salt. The designed PANI efficiently exposes the surface of rGO sheets and stabilizes metal nanoparticles. Consequently, the Pt@PANI-rGO catalyst exhibits good reusability, durability and high catalytic performance for dimethylamine borane dehydrogenation reaction. The structure morphology and properties of Pt@PANI-rGO NPs were characterized by using several different techniques such as UV-Vis, XPS, TEM, XRD and HR-TEM-EDX analyses. This newly prepared catalyst can be reused again at low concentrations and temperature. They showed a high turnover frequency (42.94 h(-1)) and low Ea value of 15.1 +/- 2 kJ/mol for DMAB dehydrocoupling in the ambient conditions. The proposed nano architecture offers a new pathway to promote the performances of rGO in various applications; moreover, this work provides a powerful and universal synthetic strategy for such an architecture. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.