• 文献标题:   Effects of high-shear mixing and the graphene oxide weight fraction on the electrochemical properties of the GO/Ni(OH)(2) electrode
  • 文献类型:   Article
  • 作  者:   YUAN YN, LIU ZY, WEI B, YANG ZY, WANG LD, FEI WD
  • 作者关键词:  
  • 出版物名称:   DALTON TRANSACTIONS
  • ISSN:   1477-9226 EI 1477-9234
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   0
  • DOI:   10.1039/c9dt04525b
  • 出版年:   2020

▎ 摘  要

A high-shear mixer was used in the process of chemical precipitation to prepare graphene oxide (GO) and Ni(OH)(2) composites with different weight fractions of GO from 0 wt% to 2.6 wt%. The GO/Ni(OH)(2) composite with 1.5 wt% GO prepared by high-shear mixing (1.5GO/Ni(OH)(2)-H) displayed a high specific capacitance (1836 F g(-1) at 2 mV s(-1)), which was beyond that (1581 F g(-1) at 2 mV s(-1)) of GO/Ni(OH)(2) obtained by impeller agitator stirring (1.5GO/Ni(OH)(2)-M). 1.5GO/Ni(OH)(2)-H also showed excellent cycling stability, retaining 91.7% of its initial specific capacitance after 2000 cycles. Furthermore, the asymmetric device (the 1.5GO/Ni(OH)(2)-H as the positive electrode and active carbon as the negative electrode) exhibited a high energy density of 41.2 W h kg(-1) at a power density of 1500 W kg(-1) with a voltage of 1.5 V. In addition, the effects of high-shear mixing and impeller agitator stirring on the microstructures and electrochemical properties of the composites were discussed, which indicated that high-shear mixing could exfoliate graphene oxide and restrain the grain growth of Ni(OH)(2), thus leading to excellent electrochemical performance.