▎ 摘　　要

Substrate adsorption-desorption is an important aspect in hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) catalysis process. The B and N are two neighboring elements of C which has Lewis acid and base characteristics. However, any thorough investigation has not been probed till date to understand the effect of simultaneous and individual incorporation of these Lewis acid and base centers in graphene towards electrocatalytic activity. In this investigation it was found that the incorporation of B and N in reduced graphene oxide (rGO) facilitated substrate adsorption-desorption and also modulated lattice parameters and electronic structure of it. Although N doped rGO showed better substrate adsorption efficiency in HER however, the substrate diffusion was sluggish in this case. Despite of moderate substrate adsorption efficiency of B and N-doped rGO, it showed better HER catalytic activity due to faster substrate diffusion and achieved 550 mA cm(-2) current density at 327 mV overpotential. The B-doped rGO showed better substrate adsorption efficiency in OER. However, due to better charge transfer efficiency of N-doped rGO, it showed superior OER catalytic activity as OER was governed by charge transfer kinetics. In addition to electrocatalytic efficiency, the mechanistic of the electrocatalysis process also altered due to the simultaneous and individual incorporation of Lewis acid and base centers. (C) 2020 Elsevier Ltd. All rights reserved.