• 文献标题:   In situ synthesis of poly(ethylene terephthalate)/graphene composites using a catalyst supported on graphite oxide
  • 文献类型:   Article
  • 作  者:   FENG RC, GUAN GH, ZHOU W, LI CC, ZHANG D, XIAO YN
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   27
  • DOI:   10.1039/c0jm03600e
  • 出版年:   2011

▎ 摘  要

An efficient method was developed for the in situ synthesis of poly(ethylene terephthalate)/graphene composites by using a polycondensation catalyst supported on graphite oxide (GO-Cat). The GO-Cat was prepared by loading a catalyst of titanium dioxide/silicon dioxide nanoparticles on organofunctionalized graphene oxide sheets, and was characterized by transmission electron microscopy and X-ray photoelectron spectroscopy. During the in situ polycondensation process, nanoscale dispersion and thermal reduction of graphene oxide were achieved simultaneously. The composites obtained exhibited a rather low electrical percolation threshold due to the homogeneous dispersion of graphene sheets within the matrix and the effective reduction of graphene oxide in the polycondensation process.