• 文献标题:   Synthesis of ternary graphene/molybdenum oxide/poly(p-phenylenediamine) nanocomposites for symmetric supercapacitors
  • 文献类型:   Article
  • 作  者:   LI D, LIU YR, LIN BP, LAI CW, SUN Y, YANG H, ZHANG XQ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Southeast Univ
  • 被引频次:   8
  • DOI:   10.1039/c5ra18979a
  • 出版年:   2015

▎ 摘  要

A novel ternary graphene/molybdenum oxide/poly(p-phenylenediamine) nanocomposite (GMP) has been successfully synthesized via a two-step process including the generation of binary graphene/MoO3 composites through a hydrothermal method and chemical polymerization of p-phenylenediamine (pPD) monomer. When the feed ratio of pPD to Na2MoO4 center dot 2H(2)O is 1, the resulting composite (GMP-1.0) possesses superior electrochemical performance with a maximum specific capacitance of 1042.6 F g(-1) at 1 A g(-1) in a three-electrode system and 418.5 F g(-1) at 1 A g(-1) in a two-electrode system. Its energy density achieves 24.56 W h kg(-1) at a power density of 325 W kg(-1), and 6.8 W h kg(-1) at a high power density of 3263 W kg(-1). Furthermore, the ternary composite retains 86.7% of the initial capacitance after 3000 cycles, indicating its excellent cycling stability.