• 文献标题:   A note on using expanded graphite for achieving energy- and time-efficient production of graphene nanoplatelets via liquid phase exfoliation
  • 文献类型:   Article
  • 作  者:   AWADA H, KONTOPOULOU M, DOCOSLIS A
  • 作者关键词:   critical specific energy, graphene nanoplatelet, liquid phase exfoliation, shear mixing
  • 出版物名称:   CANADIAN JOURNAL OF CHEMICAL ENGINEERING
  • ISSN:   0008-4034 EI 1939-019X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/cjce.24586 EA SEP 2022
  • 出版年:   2023

▎ 摘  要

Although easily scalable, the production of graphene nanoplatelets (GNP) by the means of liquid-phase exfoliation of graphite flakes (GF) remains an energy- and time-intensive process. In this work, we demonstrate that significant time and energy can be saved in GNP production when employing expanded graphite (EG) in a surfactant-assisted liquid phase exfoliation process. Owing to its increased interlayer distance, the exfoliation of EG can be accomplished in a much shorter time (<30 min) compared to GF (approximately 7 h in the present case). Moreover, the energy required for the EG exfoliation is close to 80-fold lower than that for GF exfoliation. Monitoring of the mean lateral dimension, specific surface area, and graphite flake-to-GNP transition during exfoliation was performed experimentally using several analytical techniques. The EG-derived GNPs are produced much faster and require less energy for exfoliation compared to GF, thus making it a more efficient alternative technique.