• 专利标题:   Method for preparing polypyrrole/graphene oxide composite material, involves dissolving graphene oxide in de-ionized water, treating ultrasonically and adding sodium hydroxide solution, followed by reacting, cooling and washing.
  • 专利号:   CN106531472-A, CN106531472-B
  • 发明人:   FAN X, CHEN W, PANG S, LI Y, FANG D
  • 专利权人:   UNIV GUILIN TECHNOLOGY, UNIV GUILIN TECHNOLOGY
  • 国际专利分类:   B82Y030/00, H01G011/24, H01G011/36, H01G011/46, H01G011/48, H01G011/86
  • 专利详细信息:   CN106531472-A 22 Mar 2017 H01G-011/86 201736 Pages: 8 Chinese
  • 申请详细信息:   CN106531472-A CN11068192 29 Nov 2016
  • 优先权号:   CN11068192

▎ 摘  要

NOVELTY - A polypyrrole/graphene oxide composite material preparing method involves dissolving graphene oxide in de-ionized water, treating ultrasonically and adding sodium hydroxide solution to obtain graphene oxide solution. The graphene oxide solution is added with three-dimensional porous polypyrrole, stirred, added with potassium permanganate solution and manganese(II) sulfate solution, stirred to obtain mixed solution. The mixed solution is transferred into a reaction kettle and cooled. The resultant product is washed with de-ionized water to neutral and dried to obtain the finished product. USE - Method for preparing polypyrrole/graphene oxide composite material. ADVANTAGE - The method enables preparing polypyrrole/graphene oxide composite material with excellent circulation performance, high energy density and power density, in simple, eco-friendly and reliable manner. DETAILED DESCRIPTION - A polypyrrole/graphene oxide composite material preparing method involves dissolving graphene oxide in de-ionized water, treating ultrasonically for 10 minutes and adding sodium hydroxide solution to obtain graphene oxide solution. The graphene oxide solution is added with three-dimensional porous polypyrrole, stirred fully, added with potassium permanganate solution and manganese(II) sulfate solution, stirred uniformly for 8 hours to obtain mixed solution. The mixed solution is processed ultrasonically for 5 minutes, transferred into a reaction kettle, reacted at 185 degrees C for 4 hours and cooled naturally to room temperature to obtain resultant product. The resultant product is washed with de-ionized water to neutral and dried to obtain the finished product, where the three-dimensional porous polypyrrole with graphene oxide has mass ratio of 0.1-4:1, the ratio of the manganese(II) sulfate solution to the potassium permanganate solution is 9:1, the ratio of manganese(II) sulfate solution and sodium hydroxide solution is 3:5, and the mass ratio of the manganese oxide and the graphene oxide is 0.05-0.5:1.