• 专利标题:   Perfluorosulfonic acid ion exchange membrane used in fuel cells, comprises perfluorosulfonic acid resin masterbatch doped with sulfonated graphene, where perfluorosulfonic acid resin is extruded and compounded with reinforced mesh cloth.
  • 专利号:   CN111921567-A
  • 发明人:   ZOU Y, GONG S, WANG L, FENG W, ZHANG Y
  • 专利权人:   SHANDONG DONGYUE POLYMER MATERIAL CO LTD
  • 国际专利分类:   B01J047/00
  • 专利详细信息:   CN111921567-A 13 Nov 2020 B01J-047/00 202000 Pages: 9 Chinese
  • 申请详细信息:   CN111921567-A CN10573678 22 Jun 2020
  • 优先权号:   CN10573678

▎ 摘  要

NOVELTY - Perfluorosulfonic acid ion exchange membrane comprises perfluorosulfonic acid resin masterbatch doped with sulfonated graphene, where the perfluorosulfonic acid resin is melted and extruded into a film and compounded with the reinforced mesh cloth. USE - The perfluorosulfonic acid ion exchange membrane is useful in fuel cells, water electrolysis, electrodialysis and flow batteries. ADVANTAGE - The membrane improves proton conductivity, improves the tensile strength and improves dimensional stability of the membrane. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing the membrane, involving (a) uniformly mixing sulfonated graphene and perfluorosulfonic acid resin, and melt-extruding to obtain sulfonated graphene-doped perfluorosulfonic acid resin masterbatch, (b) uniformly mixing the masterbatch with perfluorosulfonic acid resin, and melt-extruding to obtain a sulfonated graphene-doped perfluorosulfonic acid based membrane, (c) using a continuous vacuum composite process, and arranging the reinforced mesh on the surface or inside of the base membrane to obtain the membrane, (d) soaking the membrane doped with sulfonated graphene in an alkali metal hydroxide solution, and hydrolyzing to obtain transformed sulfonated graphene doped enhanced perfluorosulfonic acid membrane, and (e) soaking the membrane in an acid solution, and rinsing with deionized water to obtain the membrane.