• 专利标题:   Preparation of composite material useful as cathode material in sodium-ion battery, involves ultrasonically treating graphene oxide aqueous solution, adding tin(IV) chloride pentahydrate solution and urea and heating, and annealing.
  • 专利号:   CN106532014-A
  • 发明人:   SUN X, LI X, ZHENG C, HU X
  • 专利权人:   UNIV TIANJIN
  • 国际专利分类:   B82Y040/00, C01G019/02, H01M004/36, H01M004/48
  • 专利详细信息:   CN106532014-A 22 Mar 2017 H01M-004/36 201738 Pages: 9 Chinese
  • 申请详细信息:   CN106532014-A CN11217654 26 Dec 2016
  • 优先权号:   CN11217654

▎ 摘  要

NOVELTY - The preparation method of composite material using graphene oxide and tin dioxide nanoparticles involves weighing 0.1-0.3 g/l graphene oxide aqueous solution, ultrasonically treating and then magnetically stirring, adding 0.25-1 mol/l tin(IV) chloride pentahydrate solution to the stirred graphene oxide aqueous solution, uniformly mixing, adding 2.5-5 g/l urea to the mixture and then ultrasonically treating, heating the mixture at 170-190 degrees C and then maintaining the temperature for 12-36 hours, reacting the mixture and then cooling to room temperature, and annealing. USE - The method is useful for preparation of composite material, which is useful as cathode material in sodium-ion battery. ADVANTAGE - The method enables preparation of composite material with excellent electrochemical stability and electrical conductivity. The composite material provides excellent electrochemical properties to the sodium-ion battery. DETAILED DESCRIPTION - The preparation method of composite material using graphene oxide and tin dioxide nanoparticles involves weighing 0.1-0.3 g/l graphene oxide aqueous solution, ultrasonically treating and then magnetically stirring, adding 0.25-1 mol/l tin(IV) chloride pentahydrate solution to the stirred graphene oxide aqueous solution in a volume ratio of 3:1, uniformly mixing, ultrasonically treating the mixture, adding 2.5-5 g/l urea to the mixture and then ultrasonically treating, placing the mixture in a PTFE hydrothermal reactor and then sealing, heating the mixture at 170-190 degrees C and then maintaining the temperature for 12-36 hours, reacting the mixture and then cooling to room temperature, washing the mixture using deionized water and ethanol and then drying, and annealing under argon gas atmosphere.