• 专利标题:   Preparation of composite material involves mixing obtained aqueous phase three-dimensional graphene oxide solution and oil phase comprising aniline and chloroform to obtain nanowire composite material, stirring, and reacting in autoclave.
  • 专利号:   CN108010728-A
  • 发明人:   FAN X, ZHANG W, XIE Y, PANG S, CHEN W, FANG D
  • 专利权人:   UNIV GUILIN TECHNOLOGY
  • 国际专利分类:   B82Y030/00, B82Y040/00, H01G011/24, H01G011/30, H01G011/36, H01G011/46, H01G011/48
  • 专利详细信息:   CN108010728-A 08 May 2018 H01G-011/24 201846 Pages: 8 Chinese
  • 申请详细信息:   CN108010728-A CN11158596 20 Nov 2017
  • 优先权号:   CN11158596

▎ 摘  要

NOVELTY - Preparation of composite material involves dissolving three-dimensional (3D) graphene oxide in deionized water and ultrasonically stirring for 10 minutes to obtain aqueous phase 3D graphene oxide solution, dissolving purified aniline in chloroform to form an oil phase, mixing oil phase and aqueous phase, reacting at 0-5 degrees C for 24 hours by interfacial polymerization to obtain oil-water interface with appearance of dark green solution, filtering, washing, drying at 60 degrees C for 12 hours to obtain graphene oxide/polyaniline nanowire composite material, dissolving nanowire composite material in deionized water and stirring in potassium permanganate and manganese (II) sulfate solution for 5 minutes to obtain mixture, transferring to autoclave and reacting to 180 degrees C for 4 hours, cooling to obtain mixed solution, adding sodium hydroxide solution to mixed solution, ultrasonically processing for 5 minutes, reacting at 180 degrees C for 2 hours, cooling, washing with deionized water, and drying. USE - Preparation of composite material. DETAILED DESCRIPTION - The mass ratio of purified aniline to three-dimensional graphene oxide is 0.1-4:1. The mass ratio of manganese (II) sulfate and sodium hydroxide is 3:5. The mass ratio of manganese (II) sulfate to potassium permanganate is 9:1. The mass ratio of manganese oxide to three-dimensional graphene oxide is 0.05-0.5:1. The mass ratio of manganese dioxide and trimanganese tetroxide in the manganese oxide is 1:1.