• 专利标题:   Preparation of modified graphene suspension involves preparing graphite oxide sol using graphite oxide and water, adding to reducing-agent solution, reacting, filtering by alcohol, dispersing filtered solid in alcohol, and centrifuging.
  • 专利号:   CN102226951-A, CN102226951-B
  • 发明人:   LI Y, LIU Y, WANG M, WEN Y, YANG Y
  • 专利权人:   CHINESE ACAD SCI SHANXI INST COAL CHEM
  • 国际专利分类:   H01B001/04, H01B013/00
  • 专利详细信息:   CN102226951-A 26 Oct 2011 H01B-001/04 201211 Pages: 6 Chinese
  • 申请详细信息:   CN102226951-A CN10072746 23 Mar 2011
  • 优先权号:   CN10072746

▎ 摘  要

NOVELTY - Graphite oxide is crushed into fine powder, suspension is prepared using water, ultrasonically processed, centrifuged, and unstable impurities are removed, to obtain graphite oxide sol. Reducing agent is dissolved in water or amide-containing organic solvent to prepare reducing-agent solution, obtained graphite oxide sol is added, heated and reacted to obtain reaction mixture, which is washed using alcohol and filtered. Filtered solid is dispersed in alcohol or amide-containing organic solvent, ultrasonically processed, and centrifuged, to obtain modified graphene suspension liquid. USE - Preparation of modified graphene suspension. ADVANTAGE - The modified graphene suspension has improved dispersibility in alcohol and amide-containing organic solvent, and is prepared by simple method. DETAILED DESCRIPTION - Graphite oxide is crushed into fine powder having grain size of 5-40 mu m, suspension (0.5-3 mg/ml) is prepared using water, ultrasonically processed for 30-100 minutes with power of 35-100 W, centrifuged, and unstable impurities in suspension liquid are removed to obtain graphite oxide sol. Reducing agent is dissolved in water or amide-containing organic solvent to prepare reducing-agent solution (6-15 mg/ml), obtained graphite oxide sol (0.5-3 mg/ml) is added, heated and reacted at 30-300 degrees C for 4-20 hours to obtain reaction mixture, which is washed using alcohol and filtered. Filtered solid is dispersed in alcohol or amide-containing organic solvent, ultrasonically processed for 30-180 minutes with power of 35-100 W, and centrifuged to obtain modified graphene suspension liquid. The volume ratio of reducing agent and graphite oxide sol is 0.5-1:1-1.5.