• 专利标题:   Graphene oxide-aromatic copolyester used in food and medicine, comprises graphene oxide, aliphatic dihydric alcohol, dibasic acid or dimethyl ester, catalyst and stabilizing agent.
  • 专利号:   CN103642016-A, CN103642016-B
  • 发明人:   XU Y, JIAO J, LI J, ZENG X, XIA S, YUAN R, ZHAO W, ZHONG Y
  • 专利权人:   KINGFA SCI TECHNOLOGY CO LTD, ZHUHAI WANTONG CHEM CO LTD, KINGFA SCI TECH CO LTD, ZHUHAI WANTONG CHEM CO LTD
  • 国际专利分类:   C08G063/189, C08G063/199, C08G063/85, C08K003/04, C08K009/04, C08L067/02
  • 专利详细信息:   CN103642016-A 19 Mar 2014 C08G-063/199 201432 Pages: 9 Chinese
  • 申请详细信息:   CN103642016-A CN10587114 21 Nov 2013
  • 优先权号:   CN10587114

▎ 摘  要

NOVELTY - Graphene oxide-aromatic copolyester comprises (in pts.wt.): graphene oxide (2-10), aliphatic dihydric alcohol (40-65), dibasic acid or dimethyl ester (32-57), catalyst (0.1-2) and stabilizing agent (0.1-1.8). USE - Graphene oxide-aromatic copolyester used in food and medicine. ADVANTAGE - The graphene oxide-aromatic copolyester is biodegradable and eco-friendly. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing graphene oxide-aromatic copolyester, which involves: (A) pre-treating graphene oxide and then mixing the graphene oxide into water; (B) ultrasonically dispersing the mixed material for 20-50 minutes and then adding aliphatic dihydric alcohol to the dispersed material; (C) stirring the obtained material at 155-180 degrees C and then washing the stirred material with distilled water to obtain the graphene oxide-aliphatic dihydric alcohol solution; (D) adding dibasic acid or dimethyl ester to the graphene oxide-aliphatic dihydric alcohol solution and then adding the obtained material to reaction vessel in presence of nitrogen at 170-210 degrees C; (E) adding catalyst to the obtained material and then performing ester exchange reaction for conversion of more than 90% material; (F) adding stabilizing agent to the obtained material at 235-245 degrees C and then performing condensation polymerization under regulating vacuum degree of 50-100 Pascal for 3.5-6 hours; and (G) passing nitrogen to the obtained material at normal pressure and then discharging the obtained material to obtain desired product.