• 专利标题:   Graphene oxide hybrid multi-wall self-lubricating micro/nano capsule comprises ionic liquid as core material and multi-layer graphene oxide hybrid system as wall material.
  • 专利号:   CN110681324-A
  • 发明人:   LI H, LI Z, CHEN S, WANG H, FENG Y, MA Y, ZHANG M, SHI N
  • 专利权人:   UNIV NORTHEAST PETROLEUM
  • 国际专利分类:   B01J013/02, C08G018/32
  • 专利详细信息:   CN110681324-A 14 Jan 2020 B01J-013/02 202012 Pages: 15 Chinese
  • 申请详细信息:   CN110681324-A CN10991105 18 Oct 2019
  • 优先权号:   CN10991105

▎ 摘  要

NOVELTY - Graphene oxide hybrid multi-wall self-lubricating micro/nano capsule comprises ionic liquid as core material and multi-layer graphene oxide hybrid system as wall material, where the structure of multilayer graphene oxide hybrid system from the inside to the outside comprising polyurea/graphene oxide/(polyethyleneimine/graphene oxide)n, here n represents the number of layers of polyethyleneimine/graphene oxide , and N greater than or equal to 1 (natural number). USE - Used as graphene oxide hybrid multi-wall self-lubricating micro/nano capsule. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing graphene oxide hybrid multi-wall self-lubricating micro/nano capsule comprising (i) forming mixture comprising graphene oxide, ionic liquid, and water, (ii) mixing the mixture with isocyanate monomer, then adding chain extender, heating the reaction to obtain polyurea/graphene oxide double-walled micro-nanocapsule coated with ionic liquid, (iii) forming mixed system comprising polyethyleneimine, dopamine hydrochloride, and buffer solution, (iv) mixing the micro-nanocapsules obtained in the step (ii) with mixing system obtained in the step (iii), and reacting at room temperature to obtain dopamine-polyethyleneimine modified polyurea/graphene oxide double-walled micro-nanocapsules, and (v) mixing with aqueous graphene oxide solution, reacting under stirring to obtain core material as ionic liquid.