• 专利标题:   Nitrogen-doped graphene loading palladium/nickel catalyst comprises nickel sulfate hexahydrate, nitrogen-doped graphene, potassium borohydride and palladium(II) chloride solution.
  • 专利号:   CN106268901-A
  • 发明人:   LIU Y
  • 专利权人:   LIU Y
  • 国际专利分类:   B01J027/24
  • 专利详细信息:   CN106268901-A 04 Jan 2017 B01J-027/24 201711 Pages: 12 Chinese
  • 申请详细信息:   CN106268901-A CN10576694 18 Jul 2016
  • 优先权号:   CN10576694

▎ 摘  要

NOVELTY - Nitrogen-doped graphene loading palladium/nickel catalyst comprises 1 pts. wt. nickel sulfate hexahydrate, 4-6 pts. wt. nitrogen-doped graphene and 20-25 pts. wt. potassium borohydride and 0.05 mol/l palladium(II) chloride solution, where molar ratio between nickel and palladium is 1:2-4. USE - Used as nitrogen-doped graphene loading palladium/nickel catalyst. ADVANTAGE - Nitrogen-doped graphene loading palladium/nickel catalyst has larger desorption peak area and excellent catalytic activity, higher oxidation-reduction catalytic properties, stability and greater catalyst electrochemically active surface area. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing nitrogen-doped graphene loading palladium/nickel catalyst comprising (i) adding nitrogen-doped graphene into distilled water and sonicating to disperse uniformly to obtain nitrogen-doped graphene solution, (ii) adding potassium borohydride to the distilled water to dissolving to obtain potassium borohydride solution, (iii) adding palladium(II) chloride solution and nickel sulfate hexahydrate to the solution of nitrogen-doped graphene and sonicating, (iv) adding solution of potassium borohydride prepared in step (ii) to step (iii) resulting solution, and then reacting at 40-55 degrees C under nitrogen protection for 5-7 hours, and (v) subjecting the product after the reaction of step (iv) to filtration, filtering, washing and drying to obtain final product.