• 专利标题:   Preparing molybdenum/graphene catalyst used in lithium-air battery, comprises ultrasonically dispersing graphite oxide in deionized water, and mixing sodium borohydride and de-ionized water into obtained graphite oxide dispersion liquid.
  • 专利号:   CN103007927-A
  • 发明人:   YIN F, WANG L, LI G, CHEN B
  • 专利权人:   UNIV BEIJING CHEM TECHNOLOGY CHANGZHOU
  • 国际专利分类:   B01J023/42
  • 专利详细信息:   CN103007927-A 03 Apr 2013 B01J-023/42 201363 Pages: 5 Chinese
  • 申请详细信息:   CN103007927-A CN10541075 13 Dec 2012
  • 优先权号:   CN10541075

▎ 摘  要

NOVELTY - Preparing molybdenum/graphene catalyst comprises e.g. ultrasonically dispersing graphite oxide in deionized water to form 0.05-1 wt.% of graphite oxide dispersion liquid, adding chlorine and molybdenum acid (5-50 wt.%) into potassium hydroxide aqueous solution (0.5-4 M) to adjust pH value to 9-13, adding and uniformly mixing sodium borohydride and de-ionized water into graphite oxide dispersion liquid, and then reducing the solution 1-18 hours, filtering and washing with de-ionized water, and drying obtained product at 60-100 degrees C for 6-24 hours using sodium borohydride reduction method. USE - The molybdenum/graphene catalyst is useful in a lithium-air battery (claimed). ADVANTAGE - The catalyst prepared has excellent catalytic performance of lithium-air battery related electro-catalysis reaction. DETAILED DESCRIPTION - Preparing molybdenum/graphene catalyst comprises either ultrasonically dispersing graphite oxide in deionized water to form 0.05-1 wt.% of graphite oxide dispersion liquid, adding chlorine and molybdenum acid (5-50 wt.%) into a potassium hydroxide aqueous solution (0.5-4 M) to adjust pH value to 9-13, adding and uniformly mixing sodium borohydride and de-ionized water into graphite oxide dispersion liquid, where mass ratio of the sodium borohydride to the graphite oxide dispersion liquid is 1:1-1:5, and the de-ionized water to the graphite oxide dispersion liquid is 1:1-5:1, and then reducing the solution for 1-18 hours, filtering and washing obtained product by deionized water, and drying obtained product at 60-100 degrees C for 6-24 hours using sodium borohydride reduction method, or ultrasonically dispersing graphite oxide in ethylene glycol, adding chlorine and molybdenum acid into potassium hydroxide aqueous solution, uniformly mixing to adjust the pH value of the solution and then reducing at 90-150 degrees C for 3-12 hours, filtering and washing with de-ionized water, and drying obtained product using ethylene glycol reducing method.