• 专利标题:   Producing optically transparent and electrically conductive film, used e.g. in LED, comprises dispersing metal nanowires in graphene oxide gel, dispensing and depositing formed suspension onto supporting substrate and removing liquid medium.
  • 专利号:   US2014231718-A1, US9530531-B2
  • 发明人:   LIN Y, ZHAMU A, JANG B Z
  • 专利权人:   LIN Y, ZHAMU A, JANG B Z, NANOTEK INSTR INC, LIN Y, ZHAMU A, JANG B Z
  • 国际专利分类:   H01B001/02, H01B013/30, B05D001/12, B05D001/24, B05D005/12, C23C004/04, C23C004/12, H01B001/04, H01B001/08, H05K003/12
  • 专利详细信息:   US2014231718-A1 21 Aug 2014 H01B-013/30 201459 Pages: 16 English
  • 申请详细信息:   US2014231718-A1 US815317 21 Feb 2013
  • 优先权号:   US815317

▎ 摘  要

NOVELTY - Producing an optically transparent and electrically conductive film, comprises: (a) providing a graphene oxide gel prepared from oxidation of a graphitic material in an oxidizing medium, where the graphene oxide gel contains graphene oxide molecules dissolved in a liquid medium; (b) dispersing metal nanowires in the graphene oxide gel to form a suspension; (c) dispensing and depositing the suspension onto a supporting substrate; and (d) removing the liquid medium from the suspension to form the optically transparent and electrically conductive film. USE - The process is useful for producing an optically transparent and electrically conductive film, which is useful as an electrode in electro-optic device, which is a photovoltaic or solar cell, LED, photo-detector, touch screen, electro-wetting display, LCD, plasma display, LED display, a TV screen, a computer screen, or a mobile phone screen (all claimed). ADVANTAGE - The process produces a film that: exhibits an optical transparence of not less than 85% and sheet resistance of not greater than 100 ohm/square (preferably not greater than 50 ohm/square), an optical transparence of not less than 90% and sheet resistance of not greater than 200 ohm/square (preferably not greater than 100 ohm/square), or an optical transparence of not less than 95% and sheet resistance of not greater than 100 ohm/square (claimed); is transparent and has high electric conductivity or low sheet resistance; and is flexible, durable, mechanically strong, environmentally stable, and potentially much less expensive. DETAILED DESCRIPTION - Producing an optically transparent and electrically conductive film, comprises: (a) providing a graphene oxide gel prepared from oxidation of a graphitic material in an oxidizing medium where the graphene oxide gel contains graphene oxide molecules dissolved in a liquid medium; (b) dispersing metal nanowires in the graphene oxide gel to form a suspension; (c) dispensing and depositing the suspension onto a supporting substrate; and (d) removing the liquid medium from the suspension to form the optically transparent and electrically conductive film, which is composed of metal nanowires and graphene oxide having a metal nanowire-to-graphene oxide weight ratio of 1/99 to 99/1, where the metal nanowires contain no surface-borne metal oxide or metal compound and the film exhibits an optical transparence of not less than 80% and sheet resistance of not greater than 300 ohm/square. An INDEPENDENT CLAIM is also included for the optically transparent and electrically conductive film produced by the process, where the film is composed of metal nanowires and reduced graphene oxide with a metal nano-wire-to-reduced graphene oxide weight ratio of 1/9 to 9/1