• 专利标题:   Hollow fiber solvent-resistant nano-filtration membrane useful e.g. for separation and purification of organic solvent system, comprises base film and separation skin layer, where base film material is polyimide of generating crosslinking reaction with polyamine compound.
  • 专利号:   CN115709001-A
  • 发明人:   LIU S, LV X, JIANG Y, LI S, SU J, SU B
  • 专利权人:   UNIV CHINA OCEAN
  • 国际专利分类:   B01D061/02, B01D067/00, B01D069/02, B01D069/08, B01D069/12, B01D071/56, B01D071/64
  • 专利详细信息:   CN115709001-A 24 Feb 2023 B01D-067/00 202321 Chinese
  • 申请详细信息:   CN115709001-A CN10967119 23 Aug 2021
  • 优先权号:   CN10967119

▎ 摘  要

NOVELTY - Hollow fiber solvent-resistant nano-filtration membrane comprises a base film and a separation skin layer. The base film material is polyimide or comprises imide groups capable of crosslinking with polyamine compounds. The separation skin layer is polyamide and/or polyimide. The separation skin layer comprises graphene oxide (GO) nanomaterials. USE - The hollow fiber solvent-resistant nano-filtration membrane is useful for the separation and purification of organic solvent systems, and solution systems containing both water and organic solvent (claimed). ADVANTAGE - The membrane regulates interfacial polymerization process by doping graphene oxide in the aqueous phase monomer solution of interfacial polymerization, provides channel for fast solvent transfer, has improved separation performance, adopts low-concentration interfacial polymerization monomers and role of graphene oxide in regulating interfacial polymerization, and has extremely low roughness, and good performance. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparation method of hollow fiber solvent-resistant nano-filtration membrane using aqueous phase monomer solution comprising aromatic diamine compound, and aromatic diamine compound comprises m-phenylenediamine, p-phenylenediamine, and other aromatic compounds containing two amine groups, aqueous phase additive comprising sodium dodecylsulfonate (SDS) or other surfactants that facilitate the uniform attachment of the solution, and the aqueous phase additive comprises triethylamine or other amine compounds.