• 专利标题:   Producing composite nano-thin film, useful e.g. in high capacitance electrode, comprises e.g. dispersing carboxylated graphene oxide and nano-particles in an organic solvent, and performing Langmuir-Blodgett film forming method.
  • 专利号:   CN103862751-A
  • 发明人:   JIANG Y, XU J, YANG Y, YANG W, YANG X
  • 专利权人:   UNIV CHINA ELECTRONIC SCI TECHNOLOGY
  • 国际专利分类:   B32B015/20, B32B009/00, C08G061/12, C08G073/02
  • 专利详细信息:   CN103862751-A 18 Jun 2014 B32B-015/20 201456 Pages: 9 Chinese
  • 申请详细信息:   CN103862751-A CN10061492 24 Feb 2014
  • 优先权号:   CN10061492

▎ 摘  要

NOVELTY - Producing composite nano-thin film, comprises (i) dispersing carboxylated graphene oxide and nano-particles in an organic solvent; (ii) spreading aqueous solution of iron ions on surface of dispersion liquid to obtain composite nano-films of graphene oxide or ferric ions or nanoparticles; (iii) performing Langmuir-Blodgett film (LB) forming method by transferring composite nano-films onto the substrate surface, and replacing ferric ion with ferric chloride; and (iv) performing chemical vapor polymerization deposition process of composite nano-thin in atmosphere of conductive polymer monomer. USE - The nano-thin film is useful in high capacitance electrode and gas-sensitive material. DETAILED DESCRIPTION - Producing composite nano-thin film, comprises (i) dispersing carboxylated graphene oxide and nano-particles in an organic solvent to obtain carboxylated graphene oxide-nano-particles dispersion liquid; (ii) spreading aqueous solution of iron ions on the surface of dispersion liquid to obtain composite nano-films of graphene oxide or ferric ions or nanoparticles; (iii) performing Langmuir-Blodgett film (LB) forming method by transferring at least a portion of composite nano-films onto the substrate surface, and replacing ferric ion with ferric chloride to obtain graphite oxide/ferric chloride/nano-particle composite nano-thin film; and (iv) performing chemical vapor polymerization deposition process of the composite nano-thin in atmosphere of conductive polymer monomer to obtain graphene oxide/conductive polymer/nano-particle composite nano thin film, and reducing the graphene oxide to obtain reduced graphene oxide/conductive polymer/nanoparticle composite nano-thin film.