• 专利标题:   Preparing sound-proof graphene EPS comprises e.g. mixing graphite and oxide intercalation agent, continuous puffing, performing simple ultrasonic peeling, and mixing graphene with alcohol, filtering and drying.
  • 专利号:   CN108084583-A
  • 发明人:   HOU S, SHEN H
  • 专利权人:   JILIN YUNTING GRAPHENE TECHNOLOGY CO LTD
  • 国际专利分类:   C08F112/08, C08F002/18, C08F002/44, C08J009/14, C08K013/06, C08K003/32, C08K005/41, C08K005/42, C08K007/24, C08K009/00, C08K009/02, C08K009/04, C08L025/06
  • 专利详细信息:   CN108084583-A 29 May 2018 C08L-025/06 201841 Pages: 11 Chinese
  • 申请详细信息:   CN108084583-A CN11228352 29 Nov 2017
  • 优先权号:   CN11228352

▎ 摘  要

NOVELTY - Preparing sound-proof graphene EPS comprises (i) taking graphite of 20-150 mesh size as raw material, purity is greater than 99%, mixing graphite and oxide intercalation agent for intercalation, where the oxidative intercalation agent is acid, nitrate and/or potassium permanganate, and the mass ratio between graphite, acid, nitrate and potassium permanganate is 1:1-5:0.1-0.5:0.1-0.5, (ii) continuous puffing of intercalated graphite for 5-100 seconds in 2450 MHz high-frequency microwave, controlling output power at 50-150 KW, discharging, performing simple ultrasonic peeling into graphene layers with 3-10 layers, specific surface area of 1000-1900 m2/g, and layer thickness of 1-5 nm, and (iii) mixing graphene with alcohol for 1-5 hours, where the mass ratio between graphene and alcohol is 1:5-10, filtering and drying to obtain final product. USE - The sound-proof graphene EPS is useful in military noise reduction fields. ADVANTAGE - The graphene: disperse well in the EPS cell structure; absorbs shock waves, shock absorption energy consumption; has thermal insulation; and has a tensile strength of 0.6-0.8 Mpa, compressive strength of 0.3-0.4 Mpa, thermal conductivity of 0.0275-0.0285 W/(mK), flame retardant grade B1, sound insulation of 60 dB, and large specific surface area. DETAILED DESCRIPTION - Preparing sound-proof graphene EPS comprises (i) taking graphite of 20-150 mesh size as raw material, purity is greater than 99%, mixing graphite and oxide intercalation agent for intercalation, where the oxidative intercalation agent is acid, nitrate and/or potassium permanganate, and the mass ratio between graphite, acid, nitrate and potassium permanganate is 1:1-5:0.1-0.5:0.1-0.5, (ii) continuous puffing of intercalated graphite for 5-100 seconds in 2450 MHz high-frequency microwave, controlling output power at 50-150 KW, discharging, performing simple ultrasonic peeling into graphene layers with 3-10 layers, specific surface area of 1000-1900 m2/g, and layer thickness of 1-5 nm, and (iii) mixing graphene with alcohol for 1-5 hours, where the mass ratio between graphene and alcohol is 1:5-10, filtering and drying to obtain final product, where the sound-proof graphene EPS is composed of 35-40 wt.% styrene, 0.05-0.2 wt.% modified graphene, 0.05-0.3 wt.% initiator, 0.3-1 wt.% dispersing agent, 0.02-0.08 wt.% dispersing additive, 2-4 wt.% foaming agent and 54.42-62.58 wt.% pure water.