• 专利标题:   Preparing nitrogen-doped porous graphene used for efficient catalytic reduction of aromatic nitro compound, involves preparing graphene oxide suspension and freeze-drying; dispersing graphene oxide aerogel, nitrogen-containing precursor and activating agent into deionized water.
  • 专利号:   CN115974056-A
  • 发明人:   QI M, WANG M
  • 专利权人:   WUHAN INST TECHNOLOGY
  • 国际专利分类:   B01J027/24, C01B032/184, C01B032/19, C02F001/70, C02F101/38, C07C213/02, C07C215/76
  • 专利详细信息:   CN115974056-A 18 Apr 2023 C01B-032/184 202341 Chinese
  • 申请详细信息:   CN115974056-A CN11317485 26 Oct 2022
  • 优先权号:   CN11317485

▎ 摘  要

NOVELTY - Preparing nitrogen-doped porous graphene, involves preparing a graphene oxide suspension by improving a Hummer's method, and freeze-drying to obtain graphene oxide aerogel; uniformly dispersing the graphene oxide aerogel, a nitrogen-containing precursor and an activating agent into deionized water, and then drying and calcining at high temperature to obtain nitrogen-doped porous graphene; where the content of the first and second substances, the nitrogen-containing precursor is selected from urea, melamine and ammonium hydroxide; the activating agent is selected from potassium ferrate(VI) (KFeO4) and Potassium hydroxide (KOH). USE - Method for preparing nitrogen-doped porous graphene, used for efficient catalytic reduction of an aromatic nitro compound such as 4-nitrophenol, p-nitroaniline and p-nitrotoluene (all claimed). ADVANTAGE - The nitrogen-doped porous graphene is prepared simply and efficiently, has large specific surface area, and high nitrogen content, has better catalytic activity than catalysts reported in the literature when applied to catalytic reduction of aromatic nitro compounds, reduce the aromatic nitro compounds in aqueous solution under mild conditions, and has low cost and environmental friendliness. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a nitrogen-doped porous graphene, which is obtained by the method for preparing the nitrogen-doped porous graphene.