• 专利标题:   Composite material comprises polylactic acid, chitosan, graphene nanoplatelets, carbon fiber, glass fiber, nano-montmorillonite, silica sol, diaminodiphenylmethane tetraglycidylamine and silane coupling agent, and good toughness.
  • 专利号:   CN107841111-A
  • 发明人:   ZHENG J, CHEN X, BAI W
  • 专利权人:   HENAN ZHILIAN HUANYU INTELLECTUAL PROPERTY OPERATION CO LTD
  • 国际专利分类:   C08L067/04, C08L005/08, C08K013/06, C08K009/04, C08K009/06, C08K007/06, C08K007/14, C08K007/00, C08K003/04
  • 专利详细信息:   CN107841111-A 27 Mar 2018 C08L-067/04 201826 Pages: 6 Chinese
  • 申请详细信息:   CN107841111-A CN10834424 20 Sep 2016
  • 优先权号:   CN10834424

▎ 摘  要

NOVELTY - Composite material comprises 50-100 pts. wt. polylactic acid, 4-10 pts. wt. chitosan, 2-8 pts. wt. graphene nanoplatelets, 5-15 pts. wt. carbon fiber, 8-16 pts. wt. glass fiber, 6-10 pts. wt. nano-montmorillonite, 1-5 pts. wt. silica sol, 1-5 pts. wt. diaminodiphenylmethane tetraglycidylamine and 1-3 pts. wt. silane coupling agent. The specific surface area of the graphene nanosheet reaches 80-100m2/g and is treated with diaminodiphenylmethane tetraglycidylamine. USE - Composite material. ADVANTAGE - The composite material has good toughness, high temperature resistance, and high comprehensive mechanical strength. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for a method for preparing composite material, which involves: (A) mixing graphene nanosheets in a dimethylformamide solvent together with diaminodiphenylmethane tetraglycidylamine, mechanically stirring for 1-3 hours, and the rotation speed of 500-1500 revolution per minute, and drying in oven controlled at 45-55 degrees C continuous drying for 6 hours to obtain surface modified graphene nanosheets; (B) mixing the surface-modified graphene nanosheet with the polylactic acid particles uniformly and crushing in a three-roll mill for 20-30 minutes to obtain a polylactic acid graphene mixture; (C) mixing the poly(lactic acid) graphene mixture with chitosan, nano-montmorillonite, silane coupling agent, silica sol, and diaminodiphenylmethane tetraglycidyl amine in a high-mixer for 30 minutes, mixing uniformly by adding to the hopper of the twin-screw extruder to obtain composite; and (D) mixing the obtained composite into carbon fiber and glass fiber at a certain ratio from the fiber-adding port of the twin-screw extruder, melt blending, extruding and cooling to obtain the composite material.