• 专利标题:   Graphene/nylon 6 fiber used for tire cord, industrial fabric, net and cable such as national defense and industrial application, comprises graphene/nylon 6 nanocomposite material and additive.
  • 专利号:   CN106906534-A, CN106906534-B
  • 发明人:   GAO C, HAN Y, CHEN C
  • 专利权人:   HANGZHOU GAOXI TECHNOLOGY CO LTD
  • 国际专利分类:   C08G069/16, D01D005/08, D01F001/10, D01F006/90
  • 专利详细信息:   CN106906534-A 30 Jun 2017 D01F-006/90 201766 Pages: 8 Chinese
  • 申请详细信息:   CN106906534-A CN10131351 07 Mar 2017
  • 优先权号:   CN10131351

▎ 摘  要

NOVELTY - A graphene/nylon 6 fiber contains 100 pts. wt. graphene/nylon 6 nanocomposite material and 0-5 pts. wt. additive by high-speed melt spinning. The relative viscosity of monolayer graphene/nylon 6 nanocomposite material is 3.2-3.6. The transverse dimension of monolayer graphene grafted with nylon 6 is greater than 2 mu m. The mass ratio of graphene and nylon 6 is 0.1-0.5:100. USE - The graphene/nylon 6 fiber is used for tire cord, industrial fabric, net and cable such as national defense and industrial application. ADVANTAGE - The graphene/nylon 6 fiber has excellent mechanical property, tensile strength of greater than 8 cN/dtex and initial modulus of more than 9 GPa. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is included for preparation method of graphene/nylon 6 nanocomposite material, which involves uniformly mixing 0.1-0.5 part mass modified graphene, 0.05-0.3 parts mass molecular weight regulator, 1-10 parts mass deionized water and 100 parts mass molten caprolactam and stirring at high speed of 300-500 rpm to form dispersion, where the modified graphene has carboxyl, hydroxyl and other oxygen-containing functional group of monolayer graphene, and the ratio of carbon/oxygen is 2.5-6, mixing the dispersion in polycondensation reaction kettle under the protection of nitrogen, heating at 250-270 degrees C and reacting at pressure of 0.5-1 MPa for 3 hours, then reacting for 4 hours under vacuum, to obtain polymer melt, cooling polymer melt and granulating.