• 专利标题:   Method for coating hydroxy graphene modifiedelectrophoretic paint without nickel stainless steel comprises e.g. performing cathodic electrolytic activation and coating surface of nickel-free stainless steel.
  • 专利号:   CN112877737-A, CN112877737-B
  • 发明人:   LAI H, GUO C, CHEN M, CHEN K
  • 专利权人:   GUANGZHOU ULTRA UNION CHEM CO LTD
  • 国际专利分类:   C09D161/20, C09D177/00, C09D005/08, C09D005/44, C09D007/61, C09D007/65, C25D015/00, C25D003/06, C25D005/36, C25D007/06
  • 专利详细信息:   CN112877737-A 01 Jun 2021 C25D-003/06 202153 Pages: 11 Chinese
  • 申请详细信息:   CN112877737-A CN10039835 13 Jan 2021
  • 优先权号:   CN10039835

▎ 摘  要

NOVELTY - Method for coating hydroxy graphene modified electrophoretic paint without nickel stainless steel comprises (i) performing cathodic electrolytic activation after drawing the nickel-free stainless steel on the surface of the drawing nickel-free stainless steel to obtain a pretreated nickel-free stainless steel, electroplating a trivalent chromium coating on the surface of the pretreated nickel-free stainless steel to obtain a nickel-free stainless steel with a trivalent chromium coating, using cathodic electrophoretic coating to coat the surface of the nickel-free stainless steel with a trivalent chromium coating hydroxy graphene modified electrophoretic paint coating, where conditions for the electrolytic activation of the cathode comprises the anode is a graphite rod, the cathode is nickel-free stainless steel after wire drawing, the electrolyte includes 100-200 g/l sulfuric acid, 10-30 g/l acrylic acid and 0.1-0.5 g/l trimercapto-s-triazine. USE - The method is useful for coating hydroxy graphene modified electrophoretic paint without nickel stainless steel. ADVANTAGE - The method improves the bonding force between the coating and the nickel-free stainless steel substrate; overcome the technical defect of low corrosion resistance of nickel-free stainless steel. The paint has good lubricity, wear resistance and corrosion resistance. DETAILED DESCRIPTION - Method for coating hydroxy graphene modifiedelectrophoretic paint without nickel stainless steel comprises (i) performing cathodic electrolytic activation after drawing the nickel-free stainless steel on the surface of the drawing nickel-free stainless steel to obtain a pretreated nickel-free stainless steel, electroplating a trivalent chromium coating on the surface of the pretreated nickel-free stainless steel to obtain a nickel-free stainless steel with a trivalent chromium coating, using cathodic electrophoretic coating to coat the surface of the nickel-free stainless steel with a trivalent chromium coating Hydroxy graphene modified electrophoretic paint coating, where conditions for the electrolytic activation of the cathode comprises the anode is a graphite rod, the cathode is nickel-free stainless steel after wire drawing, the electrolyte includes 100-200 g/l sulfuric acid, 10-30 g/l acrylic acid and 0.1-0.5 g/l trimercapto-s-triazine, the current density of the cathode is 0.5-3 A/dm2, and the electrolysis time is 1-3 minutes, the conditions of the cathodic electrophoretic coating comprises the anode is a 0Cr13 stainless steel plate, the cathode is a nickel-free stainless steel with trivalent chromium plating and the coating is a hydroxy graphite modified electrophoretic paint, the hydroxygraphite modified electrophoretic paint includes 300-350 g/l electrophoretic paint and 150-200 g/l hydroxygraphene filler and the pH of the paint is 4-5, the temperature of the cathodic electrophoretic coating is 25-30 degrees C, and the tank voltage is 30-100 V and hydroxygraphene filler includes hydroxygraphene, water-based polyurethane, and water-based silane polymer. An INDEPENDENT CLAIM is also included for protective coating of nickel-free stainless steel prepared by the method as mentioned above, comprising trivalent chromium coating and a hydroxygraphene modified electrophoretic paint coating sequentially arranged on the surface of nickel-free stainless steel.