• 专利标题:   Cathode sheet useful in secondary batteries, comprises cathode material layer including cathode active material comprising carbon-based material and phosphate compound.
  • 专利号:   CN115117347-A
  • 发明人:   WANG Y, XIANG X, LI H, ZHANG Z, HU S, QIAN Y
  • 专利权人:   SHENZHEN CAPCHEM TECHNOLOGY CO LTD
  • 国际专利分类:   H01M010/0525, H01M004/133, H01M004/62
  • 专利详细信息:   CN115117347-A 27 Sep 2022 H01M-004/62 202298 Chinese
  • 申请详细信息:   CN115117347-A CN10697868 20 Jun 2022
  • 优先权号:   CN10697868

▎ 摘  要

NOVELTY - Cathode sheet comprises a cathode material layer including a cathode active material comprising carbon-based material and phosphate compound (I). The cathode sheet satisfies that 10*c*a/b is 0.2-40, the resistivity of the cathode sheet is ≤ 200 Ω.m, the liquid chromatography-mass spectrometry (LC-MS) analysis of the solution obtained after the cathode sheet is ultrasonically oscillated in the solvent shows that the characteristic peak appears in the region with a retention time of 6.5-7.5 minutes. USE - The cathode sheet is useful in secondary batteries (claimed). ADVANTAGE - The cathode sheet: overcomes the problems of insufficient SEI film stability in existing lithium-ion batteries that lead to battery cycle performance degradation and capacity fading, used in secondary battery; has low impedance, can improve the permeability of the non-aqueous electrolyte to the cathode material layer, and efficiently improve the cycle performance of the battery. DETAILED DESCRIPTION - Cathode sheet comprises a cathode material layer including a cathode active material comprising carbon-based material and phosphate compound of formula (I). The cathode sheet satisfies that 10*c*a/b is 0.2-40, the resistivity of the cathode sheet is ≤ 200 Ω.m, the liquid chromatography-mass spectrometry (LC-MS) analysis of the solution obtained after the cathode sheet is ultrasonically oscillated in the solvent shows that the characteristic peak appears in the region with a retention time of 6.5-7.5 minutes, c is mass percentage of the cathode active material in the cathode material layer, the unit is %; a is mass percentage of the compound I in the cathode material layer in %; and b is porosity of the cathode material layer in %. Either R1-R3= 1-5C alkyl group, 1-5C fluoroalkyl group, 1-5C ether groups, 1-5 fluoroether group or 2-5 C unsaturated hydrocarbon group; Or at least one of R1-R3= 2-5C unsaturated hydrocarbon group; a = 0.005-1; b = 10-50; and c = 92-98. An INDEPENDENT CLAIM is also included for secondary battery comprising an anode sheet, a non-aqueous electrolyte and the cathode sheet.