• 专利标题:   Graphene/polyurethane sponge used for modifying polysulfide sealant, is fully immersed in polyurethane sponge in graphene oxide dispersion liquid containing reducing agent ascorbic acid.
  • 专利号:   CN111116977-A
  • 发明人:   CHEN P, TAO W, ZHOU Y, NIE W, XU Y, ZENG S
  • 专利权人:   UNIV ANHUI
  • 国际专利分类:   C08G075/14, C08J009/40, C08L075/04, C09J011/08, C09J181/04, C09J009/02
  • 专利详细信息:   CN111116977-A 08 May 2020 C08J-009/40 202048 Pages: 10 Chinese
  • 申请详细信息:   CN111116977-A CN11395373 30 Dec 2019
  • 优先权号:   CN11395373

▎ 摘  要

NOVELTY - Graphene/polyurethane sponge is fully immersed in polyurethane sponge in graphene oxide dispersion liquid containing reducing agent ascorbic acid, where hydrothermal reaction reduces graphene oxide to graphene and self-assembles on the polyurethane sponge uniformly. The treated polyurethane sponge is taken out and dried, and then fully immersed in phenyl vinyl ether and finally freeze-dried to obtain the graphene/polyurethane sponge. USE - Graphene/polyurethane sponge used for modifying polysulfide sealant. ADVANTAGE - The graphene/polyurethane sponge used for modifying polysulfide sealant has significantly improved electrical conductivity and mechanical properties. DETAILED DESCRIPTION - INDEPENDENT CLAIMS are included for the following: (1) a method for preparing graphene/polyurethane sponge, which involves ultrasonic dispersing graphene oxide in deionized water with addition of ascorbic acid as a reducing agent to obtain a precursor solution, cutting the polyurethane sponge into the desired shape, fully immersing the polyurethane sponge in the precursor liquid, placing in a hydrothermal kettle to hydrothermal reaction at 110-130 degrees C for 10-12 hours to reduce graphene oxide to graphene and self-assemble on the polyurethane sponge uniformly, fully immersing the product obtained in phenyl vinyl ether for 10-12 hours, and then taking out and freeze-drying to obtain the graphene/polyurethane sponge; and (2) a method for modifying polysulfide sealant using the graphene/polyurethane sponge, which involves immersing graphene/polyurethane sponge in a polysulfide sealant system under normal temperature and vacuum conditions, fully absorbing the polysulfide sealant into the graphene/polyurethane sponge, and then finally taking out and drying to get the modified polysulfide sealant.