• 专利标题:   Rare earth graphene film comprises e.g. graphene oxide, lanthanum nitrate, cerous nitrate, didecyldimethylammonium bromide, 8-hydroxyquinoline, ammonium persulfate, thionyl chloride, cyanoethyl cellulose and methyl methacrylate.
  • 专利号:   CN109082056-A
  • 发明人:   XU M, HE T
  • 专利权人:   TONGCHENG MINGLI BORON CARBIDE PROD CO
  • 国际专利分类:   C08L033/12, C08L001/32, C08K013/02, C08K003/04, C08K003/28, C08K005/19, C08K005/3437, C08F120/14, C08F002/44, C08J005/18, C08B013/00
  • 专利详细信息:   CN109082056-A 25 Dec 2018 C08L-033/12 201915 Pages: 5 Chinese
  • 申请详细信息:   CN109082056-A CN10792627 18 Jul 2018
  • 优先权号:   CN10792627

▎ 摘  要

NOVELTY - Rare earth graphene film comprises 40-50 pts. wt. graphene oxide, 1-2 pts. wt. lanthanum nitrate, 1-2 pts. wt. cerous nitrate, 0.7-1 pts. wt. didecyldimethylammonium bromide, 0.4-1 pts. wt. 8-hydroxyquinoline, 3-4 pts. wt. linoleic acid, 0.3-0.4 pts. wt. ammonium persulfate, 100-130 pts. wt. thionyl chloride, 2-4 pts. wt. cyanoethyl cellulose, 0.1-0.4 pts. wt. Sp-80 (RTM: Polysorbate 80) and 20-30 pts. wt. methyl methacrylate. USE - Used as rare earth graphene film. ADVANTAGE - The film has improved mechanical strength. DETAILED DESCRIPTION - An INDEPENDENT CLAIM is also included for preparing rare earth graphene film, comprising (i) mixing lanthanum nitrate, cerous nitrate with 120-130 times of (based on weight of the mixed material) deionized water, and stirring uniformly to obtain rare earth solution, (ii) adding 8-hydroxyquinoline to 6-9 times of anhydrous ethanol, stirring uniformly, heating to 60-65 degrees C, adding methyl methacrylate, and stirring for 10-20 minutes to obtain ester solution, (iii) adding ammonium persulfate into 10-16 times deionized water, and stirring uniformly, (iv) mixing linoleic acid and cyanoethyl cellulose in thionyl chloride, and ultrasonically processing for 20-30 minutes to obtain fiber solution, (v) adding graphene oxide, didecyldimethylammonium bromide into rare earth solution, stirring uniformly, mixing with ester solution, then adding into a reaction kettle, then passing nitrogen gas, adjusting the temperature of the reaction kettle to 60-70 degrees C, adding ammonium persulfate aqueous solution, stirring for 3-4 hours, then discharging and cooling to obtain graphene polyester solution, and (vi) adding fiber mixed solution and graphene polyester solution into Sp-80 (RTM: Polysorbate 80), ultrasonic treating for 1-2 hours, coating uniformly on a glass plate, placing into an oven, drying at 70-75 degrees C for 10-13 hours, discharging and cooling, and then removing the film to obtain final product.