• 专利标题:   Preparation of wear-resistant rubber sole includes oscillating graphene oxide, performing centrifugal separation, concentrating, drying, pretreating graphene oxide, mixing, filtering, washing, drying, freezing, weighing and vulcanizing.
  • 专利号:   CN108250521-A
  • 发明人:   ZHANG J, XIAO X, ZHANG M
  • 专利权人:   ZHANG J
  • 国际专利分类:   C08L015/00, C08L023/28, C08L061/06, C08L009/02, C08K013/06, C08K009/06, C08K003/04, C08K009/00, C08K003/34, C08K009/02, C08K007/18, C08K003/06, C08K003/22, C08K003/36, A43B013/04
  • 专利详细信息:   CN108250521-A 06 Jul 2018 C08L-015/00 201854 Pages: 10 Chinese
  • 申请详细信息:   CN108250521-A CN11489047 30 Dec 2017
  • 优先权号:   CN11489047

▎ 摘  要

NOVELTY - Preparation of wear-resistant rubber sole includes oscillating graphene oxide, performing centrifugal separation, concentrating, drying, pretreating graphene oxide, mixing pretreated graphene oxide and silane coupling agent at 1:20-1:25, adding 100-120 pts. wt. pretreated graphene oxide, mixing, filtering, washing, drying to obtain modified graphene oxide, mixing phenolic resin and bromobutyl rubber at 1:3-1:4 to obtain mixture, mixing vitrified beads and sodium hydroxide solution at 1:3-1:5, filtering, pretreating vitrified beads, mixing pretreated vitrified beads and hydrogen peroxide at 1:3-1:5, filtering to obtain pretreated modified vitrified beads, mixing pretreated modified vitrified beads and paraffin at 1:3-1:5, adding polyethylene wax, mixing, freezing, crushing to obtain modified vitrified beads, mixing pretreated zeolite and tetraethyl orthosilicate at 1:5-1:8, filtering to obtain modified zeolite, weighing and vulcanizing in mold. USE - Method of preparing wear-resistant rubber sole. ADVANTAGE - The sole has excellent abrasion resistance. DETAILED DESCRIPTION - Preparation of wear-resistant rubber sole comprises oscillating graphene oxide, performing centrifugal separation, concentrating, drying, pretreating graphene oxide, mixing pretreated graphene oxide and silane coupling agent at 1:20-1:25, adding 100-120 pts. wt. pretreated graphene oxide, mixing, filtering, washing, drying to obtain modified graphene oxide, mixing phenolic resin and bromobutyl rubber at 1:3-1:4 to obtain mixture, mixing vitrified beads and sodium hydroxide solution at 1:3-1:5, filtering, pretreating vitrified beads, mixing pretreated vitrified beads and hydrogen peroxide at 1:3-1:5, filtering to obtain pretreated modified vitrified beads, mixing pretreated modified vitrified beads and paraffin at 1:3-1:5, adding polyethylene wax, mixing, freezing, crushing to obtain modified vitrified beads, mixing pretreated zeolite and tetraethyl orthosilicate at 1:5-1:8, filtering to obtain modified zeolite, weighing 5-10 pts. wt. nitrile rubber, 20-30 pts. wt. mixture, 15-25 pts. wt. epoxidized natural rubber, 2-4 pts. wt. sulfur, 3-5 pts. wt. plasticizer, 5-8 pts. wt. anti-aging agent, 5-8 pts. wt. nano zinc powder, 10-15 pts. wt. modified graphene oxide, 8-12 pts. wt. modified vitrified beads, 4-8 pts. wt. modified zeolite and 2-5 pts. wt. vulcanization accelerator, mixing nitrile rubber and mixture, adding epoxidized natural rubber, plasticizer and anti-aging agent, mixing, adding nano zinc powder, sulfur, modified graphene oxide, modified vitrified bead, modified zeolite and vulcanization accelerator, mixing to obtain mixed materials and vulcanizing in mold.