• 专利标题:   Preparation of plant-based graphene involves mixing bio-oil and catalyst, calcining in self-pressurizing reactor placed in high-temperature furnace, cooling, performing acid pickling to recover catalyst, and washing obtained sample.
  • 专利号:   CN104891479-A, CN104891479-B
  • 发明人:   DENG X, CHEN C, JIANG J, LU X, SUN K, ZHU G, JIA Y
  • 专利权人:   CHINESE ACAD FORESTRY INST CHEM IND FORE, INST CHEM IND FOREST PROD CHINESE ACAD
  • 国际专利分类:   C01B031/04
  • 专利详细信息:   CN104891479-A 09 Sep 2015 C01B-031/04 201619 Pages: 10 Chinese
  • 申请详细信息:   CN104891479-A CN10275731 26 May 2015
  • 优先权号:   CN10275731

▎ 摘  要

NOVELTY - Preparation of plant-based graphene involves drying agricultural and forestry biomass raw material, performing liquefaction using phenol and filtering to obtain bio-oil, mixing bio-oil and iron-series element as catalyst, adding obtained mixture into self-pressurizing reactor, sealing, then providing into high-temperature furnace, calcining, cooling, performing acid pickling to recover catalyst, washing obtained sample using deionized water and drying. The obtained plant-based graphene has conductivity of 370 s/cm, specific surface area of 760 m2/g and thickness of 1-3 nm. USE - Preparation of plant-based graphene (claimed). ADVANTAGE - The method enables economical preparation of plant-based graphene with high productivity. DETAILED DESCRIPTION - Preparation of plant-based graphene involves drying agricultural and forestry biomass raw material, performing liquefaction using phenol and filtering to remove inorganic impurities to obtain bio-oil, mixing bio-oil and iron-series element as catalyst in a mass ratio of (0.1-1):1, adding predetermined amount of obtained mixture into self-pressurizing reactor, sealing the reactor, then providing into high-temperature furnace, calcining, naturally cooling, performing acid pickling to recover catalyst, washing obtained sample using deionized water and drying. The volume of material does not exceed 1/3 of reactor volume. The obtained plant-based graphene has electroconductivity of 370 s/cm, specific surface area of 760 m2/g and thickness of 1-3 nm.