• 专利标题:   Preparing anode polysulfide buffer layer used for improving cycle performance of lithium sulfur battery comprises dispersing graphene oxide in octylamine solution, adding molybdenum trioxide and selenium dioxide, annealing, adding polyvinylidene fluoride, coating black slurry and vacuum drying.
  • 专利号:   CN114267818-A
  • 发明人:   ZHANG Y, ZHANG F, BAO S, CUI C, YU H, YOU Y
  • 专利权人:   UNIV HUAIBEI NORMAL
  • 国际专利分类:   H01M004/13, H01M050/431, H01M050/46
  • 专利详细信息:   CN114267818-A 01 Apr 2022 H01M-004/13 202279 Chinese
  • 申请详细信息:   CN114267818-A CN11601369 24 Dec 2021
  • 优先权号:   CN11601369

▎ 摘  要

NOVELTY - Preparing anode polysulfide buffer layer comprises uniformly dispersing graphene oxide in octylamine solution, transferring to a reaction kettle, then adding molybdenum trioxide and selenium dioxide, mixing uniformly at 180-200°C, reacting for 24-48 hours to obtain the precursor, then cleaning the precursor, drying, annealing and reducing for 1.5-3 hours at 380-450°C under the mixed atmosphere of hydrogen and inert gas to obtain molybdenum diselenide/reduced graphene oxide (MoSe2/rGO) composite material, adding the MoSe2/rGO composite material in a grinding body, adding polyvinylidene fluoride and N-methyl-2-pyrrolidone, grinding to mix uniformly to obtain the black slurry, then coating the black slurry on the anode surface the lithium-sulfur battery, and vacuum drying. USE - The buffer layer is useful for improving cycle performance of lithium sulfur battery as high-energy density energy storage system, and in preparing electrode sheet (claimed). ADVANTAGE - The method: uses anode polysulfide buffer layer to form good contact effect and active reaction interface; eliminates the natural degradation of the lithium sulfide battery; reduces the interface impedance between the coating and the anode; promotes reversible conversion of the discharge product to the active sulfur; and improves active sulfur utilization rate and the whole performance of the battery. DETAILED DESCRIPTION - INDEPENDENT CLAIMs are also included for: Anode polysulfide buffer layer for improving cycle performance of lithium sulfur battery. Electrode sheet. DESCRIPTION OF DRAWING(S) - The drawing shows a schematic illustration for the method for preparing anode polysulfide buffer layer for improving cycle performance of lithium sulfur battery .